Anyway, moving on to the solution (to the problem as initial worded). Its tricky to do anything involving weighing 1 coin against 2 right away, since if you weigh 1+2 against 3, even if it balances you cannot be sure that it was not the 1+3 against 4 or the 2+4 against the 6 or something. You could also try having 4 coins on one side, but that cannot work since on the second measurement you must split up those 4 coins or you cannot tell them apart. Perhaps something involving 2 vs. 2 works, but I didn't find anything. The thing that does work is to weigh the 1+2+3 against the 6. If it is imbalanced, we are done, if it is balanced then you have identified the 6 (it is the only one that can have as much mass as 3 others combined) and you have identified a group that is the {1,2,3}, since they are the only 3 light enough that a single coin could balance them.
So, in one measurement we have identified the {1,2,3}, the {4,5} and the {6}. The next measurement is to do the 6 and the 1 against the 5 and the 3.
If they are labeled correctly, the 5+3 should be heavier than the 6+1 (so, if that doesn't happen we are done). Since the 6 is identified, and the 1 must weight at least 1, the 6+1 must weigh at least 7, but since the 5+3 came out heavier, the 5 could not be any lighter and neither could the 3, so the 5 and 3 are correct. By a similar logic, the 5+3 cannot together weight more than 8, so the 1 cannot afford to be any heavier if the 6+1 is to be less than 8, thus the 1 must be the 1. That leaves the 2 and 4 both uniquely identified.
This completes the solution. I cannot prove that there aren't any other solutions, but I greatly doubt their existence.
Next, the follow-up:
A mathemagician has 8 coins, with masses 1 through 8, he knows which coin is which. He intends to prove to an audience that he knows the correct mass of at least one of the coins using a single measurement of a balance scale. What measurement can he perform to prove the mass of any one of the coins?
You may assume that the audience knows that the coins have masses 1 through 8, but they do not know which one is which. After one measurement, the mathemagician must be able to select a single coin and say "I have now proven this one is the x" for some value of x. You may also assume the audience is a bunch of mathematicians, they will not be tricked by some sort of lies.
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